纳滤分离铝锂过程研究          下载免费PDF全文

高琳  王怀有  赵有璟  王敏 《盐湖研究》2020,28(2)

本文探讨了纳滤分离Al~(3+)和Li~+的可行性,研究了含盐量和铝锂比对分离效率的影响,提出了从锂云母浸出液中分离回收锂的新方法。实验结果表明,纳滤膜对Al~(3+)和Li~+的截留率随含盐量的升高而降低,其中Li~+始终呈现负浓度梯度扩散的趋势,而Al~(3+)的截留率始终稳定在99%以上。当含盐量为45 g/L时,铝锂分离因子最高可达248.33,膜面相应Zeta电位的绝对值达到最大。随着溶液中铝锂比的变化,Al~(3+)和Li~+的截留率分别在不同铝锂比的条件下出现拐点,溶液的pH呈现先下降后上升最后下降的复杂趋势。本实验研究发现,DK膜能够在酸性环境下实现高效的铝锂分离和锂的浓缩,从而为锂云母浸出液中锂的提取提供新的思路。  相似文献   

Theory and measurement model of administrative region potential from a perspective of administrative division adjustment: Taking Chongqing city as a case study     

Wang  Kaiyong  Wang  Fuyuan 《地理学报(英文版)》2020,30(8):1341-1362

Journal of Geographical Sciences - There is a lack of basic theory and method to examine the effect of administrative division (AD) adjustment on the regional development. Based on the theory and...  相似文献   

一种旋转塑性势面模型及非关联塑性流动法则     

徐日庆  蒋佳琪  冯苏阳  鞠露莹 《岩土力学》2020,41(5):1474-1482

为了较好地描述软土塑性应变发展规律，提出了一种改进的塑性流动模型。该模型采用了与屈服函数形式相同，但具有一定倾角 的塑性势函数。土体在变形过程中，塑性流动方向会依赖于塑性势面的旋转而变化，直至达到破坏状态。通过对常规三轴试验结果的分析可以发现：在剪切过程中，塑性势面旋转角的初值 与终值 较为稳定，不受围压变化影响。在此试验观察基础上，引入了归一化的旋转角参数 以及描述土体应力状态的参数 ，在采用蛋形势函数的情况下二者具有良好的分段线性关系。利用该关系，建立了改进的塑性流动法则，只需要2个额外的模型参数。对所提出的塑性流动模型进行了验证，计算结果表明该模型能较好地反映塑性应变的变化趋势。  相似文献   

不同产地浒苔对幼刺参生长、消化和非特异性免疫的影响     

杨心愿  林承刚  宋肖跃  孙景春  杨红生 《海洋与湖沼》2018,49(5):1103-1108

为探究不同产地浒苔型饵料对幼刺参生长、消化和非特异性免疫的影响,本实验将青岛浒苔与宁波浒苔的干粉与海泥分别按一定质量比例混合,开展刺参饲喂实验,并与刺参天然饵料马尾藻进行对比。结果表明,青岛浒苔饵料和马尾藻饵料喂养的刺参的粗蛋白含量分别为14.31%±0.10%和15.43%±1.41%,显著高于宁波浒苔饵料(11.17%±0.63%),粗脂肪和灰分含量无显著差异;青岛浒苔组、宁波浒苔组和马尾藻组的增重率分别为22.65%±5.68%、3.03%±1.17%和20.47%±2.01%,特定生长率分别为(1.44±0.33)、(0.21±0.08)、(1.33±0.12)%/d,青岛浒苔组和马尾藻组刺参的增重率和特定生长率显著高于宁波浒苔组;青岛浒苔组、宁波浒苔组和马尾藻组刺参肠道淀粉酶、胃蛋白酶、胰蛋白酶和纤维素酶活力无显著差异;马尾藻组刺参体腔液碱性磷酸酶活力为(17.57±4.56)金氏单位/100mL,显著高于青岛浒苔组[(5.56±1.32)金氏单位/100mL]和宁波浒苔组[(2.83±0.75)金氏单位/100mL],超氧化物歧化酶和酸性磷酸酶活力无显著差异。由此可见,绿潮暴发时,通过打捞浒苔用以配制刺参饵料,既有助于缓解绿潮的生态灾害,又能够补充刺参饵料来源,具有广阔的生态效益和市场前景,但是其营养成分影响因素较为复杂,配制饵料时应充分考虑不同品种、采集时间和生长地点的差异,并通过一些前处理手段充分发挥浒苔的饵料价值。  相似文献   

Lateral cyclic response of an aluminum model pile in sand     

Jiunn-Shyang Chiou  Zhi-Wei Xu  Cheng-Chang Tsai  Jin-Hung Hwang 《Marine Georesources & Geotechnology》2018,36(5):554-563

Lateral cyclic load tests were performed on an aluminum model pile in dry sand. Two levels of loading were adopted to represent different service load conditions. The maximum number of loading cycles was 1,000. From the test results, it was found that the even though in the service load condition, the pile response was still affected by cyclic effects and a larger load level would produce more significant influence. In a global point of view, the lateral displacement and maximum moment increased with loading cycles, while the secant stiffness within a cycle decreased with cycles. The cyclic effect was more significant on the lateral displacement than on the moment. In a local point of view, cyclic loading would degrade the equivalent subgrade stiffness for the soil shallower than about seven times diameter. In addition, the secant subgrade stiffness within a cycle increased with loading cycles. Some experimental relationships of lateral pile response and loading cycles were built and compared with those in the literature.  相似文献   

Terrestrial discharge influences microbioerosion and microbioeroder community structure in coral reefs     

SA Mwachireya  M Carreiro-Silva  BE Hartwick  TR McClanahan 《African Journal of Marine Science》2018,40(1):25-42

Microbioerosion rates and microbioeroder community structure were studied in four Kenyan protected coral-reef lagoons using shell fragments of Tridacna giant clams to determine their response to the influence of terrestrial run-off. Fourteen different microbioeroder traces from seven cyanobacteria, three green algae and four fungi species were identified. The river discharge-impacted reef and ‘pristine’ reef showed similar composition but higher microbioeroder abundance and total cyanobacteria- and chlorophyte-bioeroded areas when compared with the other study reefs. Cyanobacteria dominated during the north-east monsoon (NEM) relative to the south-east monsoon (SEM) season, with algae and cyanobacteria being major microbioeroders in the river-impacted and pristine reefs. The rate of microbioerosion varied between 4.3 g CaCO3 m^?2 y^?1 (SEM) and 134.7 g CaCO₃ m^?2 y^?1 (NEM), and was highest in the river-impacted reef (127.6 g CaCO₃ m^?2 y^?1), which was almost double that in the pristine reef (69.5 g CaCO₃ m^?2 y^?1) and the mangrove-fringed reef (56.2 g CaCO₃ m^?2 y^?1). The microbioerosion rates measured in this study may not be high enough to cause concern with regard to the health and net carbonate production of Kenya’s coral reefs. Nevertheless, predicted increases in the frequency and severity of stresses related to global climate change (e.g. increased sea surface temperature, acidification), as well as interactions with local disturbances and their influence on bioerosion, may be increasingly important in the future.  相似文献   

Metal flux as an alternative parameter in evaluating the resource potential for co-rich ferromanganese crusts     

Hisaaki Sato 《Marine Georesources & Geotechnology》2018,36(7):768-780

We propose a geochemical parameter, “metal flux” in evaluating hydrogenetic Co-rich ferromanganese crust deposits in the Pacific seamount area, that is based on physical, chemical, and geological characterization of the integrated growth piles of crusts. We calculated the metal flux for fifteen sites from different depths ranging between 900-6000m from different seamounts. The secular and areal variations of metal flux indicate a strong geological controls, and also can be a reliable tool for estimating an economic potential of the crusts. The Co flux decreases with increasing water depth, followed by almost constant flux of Ni and Mn. The Al and Fe fluxes vary with regions, indicating higher values in the western regions near the island arc probably related to a supply from the Asian continents. The results imply that Co, a redox sensitive metal element, is controlled by redox conditions of seawater, while Fe and Al are by terrigenous input. The metal flux reflects global and regional conditions and controls the compositional diversity of metals, thus consequently, the parameter can be a reliable powerful tool to estimate or single out more potential areas.  相似文献   

环渤海地区海洋经济增长质量空间溢出效应研究   总被引：4，自引：2，他引：2  

李博  田闯  金翠  史钊源 《地理科学》2020,40(8):1266-1275

海洋经济向质量效益型转变是建设海洋强国的新要求。通过构建海洋经济?地理距离空间权重矩阵对2000—2014年环渤海地区17个沿海地级市海洋经济增长质量主体的空间交互作用及空间效应进行研究；借助空间计量模型对海洋经济增长质量空间效应影响因素进行甄别。研究表明：① 环渤海地区海洋经济增长质量主体呈显著空间相关性，存在空间交互作用；② 海洋经济增长质量存在空间溢出的正反馈效应。影响因素中对环渤海地区海洋经济增长质量的直接贡献强度排序为：海洋环境>海洋产业>海洋人才>海洋资本>海洋科技，对其他地区溢出效应影响的排序为：海洋基建>海洋人才>海洋资本。研究为环渤海地区海洋政策制定提供一定参考依据。  相似文献   

甘肃省地热资源赋存特征及潜力评价     

谢娜  喻生波  丁宏伟  张明泉 《中国地质》2020,47(6):1804-1812

甘肃省地热资源丰富，其地热资源的开发利用具有较大的潜力。本文介绍了甘肃省地热资源分布概况，结合地区构造、地热水化学特征、地热资源量及开发利用现状探讨了甘肃隆起山地对流型与沉积盆地传导型地热资源的赋存特征，并对两种类型地热资源潜力进行了分析评价。结果表明，沉积盆地地热资源分布于河西、陇西及陇东盆地等，热储类型为裂隙型和孔隙型，热储层自元古宙至新生代均有发育，岩性以砂岩为主；隆起山地型地热资源主要分布于祁连山和西秦岭造山带，热储类型为断裂破碎带，岩性以花岗岩为主；通过潜力计算得知，全省热量开采系数≥0.4的仅占29.17%，表明目前甘肃地热资源开采程度较低，开采潜力较大。  相似文献   

2017年春季季风间期南海中北部浮游植物生长与微型浮游动物摄食     

陈大伟  郭聪聪  余凌晖  鲁远征  孙军 《海洋学报(英文版)》2020,39(6):84-95

Phytoplankton growth rates and mortality rates were experimentally examined at 21 stations during the 2017 spring intermonsoon(April to early May) in the northern and central South China Sea(SCS) using the dilution technique, with emphasis on a comparison between the northern and central SCS areas which had different environmental factors. There had been higher temperature but lower nutrients and chlorophyll a concentrations in the central SCS than those in the northern SCS. The mean rates of phytoplankton growth(μ_0) and microzooplankton grazing(m) were(0.88±0.33) d~(–1) and(0.55±0.22) d~(–1) in the central SCS, and both higher than those in the northern SCS with the values of μ_0((0.81±0.16) d~(–1)) and m((0.30±0.09) d~(–1)), respectively.Phytoplankton growth and microzooplankton grazing rates were significantly coupled in both areas. The microzooplankton grazing impact(m/μ_0) on phytoplankton was also higher in the central SCS(0.63±0.12) than that in the northern SCS(0.37±0.06). The microzooplankton abundance was significantly correlated with temperature in the surface. Temperature might more effectively promote the microzooplankton grazing rate than phytoplankton growth rate, which might contribute to higher m and m/μ_0 in the central SCS. Compared with temperature, nutrients mainly affected the growth rate of phytoplankton. In the nutrient enrichment treatment,the phytoplankton growth rate(μn) was higher than μ_0 in the central SCS, suggesting phytoplankton growth in the central SCS was nutrient limited. The ratio of μ_0/μn was significantly correlated with nutrients concentrations in the both areas, indicating the limitation of nutrients was related to the concentrations of background nutrients in the study stations.  相似文献